Messi scored his second goal of the game in stunning fashion on Saturday in a 5-0 victory.
His goals completed the rout as he saved the best for last.
Leandro Paredes delivered a superb pass to Messi, who had perfect control of the ball with his chest, before kicking a bicycle kick in a super-smooth move, scoring an amazing goal.
Messi scored his first goal of the game in the 80th minute, followed by a powerful goal of the season.
He flicked the ball behind him to set up Neymar, who scored with a low shot.
Achraf Hakimi and Marquinhos were also on the scoresheet as the defending French champions started their league campaign with a big win.
Paris Saint-Germain will resume the league next Saturday when they host Montpellier.